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Bromopentaamminecobalt(III) bromide
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Bromopentaamminecobalt(III) bromide : ウィキペディア英語版
Bromopentaamminecobalt(III) bromide

Bromopentaamminecobalt(III) bromide is a cobalt coordination compound with the formula ()Br2. It is a purple, water-soluble solid.
==Synthesis and reactions==
The title compound is prepared by oxidation of a solution of cobalt(II) salts in aqueous ammonia.
:2 CoBr2 + 8 NH3 + 2 NH4Br + H2O2 → 2 ()Br2 + 2 H2O
It was first reported in the 1870s, before the structure or even formulae were understood for such complexes. This early work showed that only two thirds of the bromide groups were exchangeable with other anions such as nitrate and dithionate.
The complex undergoes aquation, meaning that bromide is displaced by water:
:()Br2 + H2O → ()Br3
This process is catalyzed by platinum.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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